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197. Metallographic Analysis of PM Fracture Surfaces  The fracture surfaces produced by breaking PM materials appear substantially different from those generated on parts made by other metalworking techniques. Although the characteristics of the fractured regions are the same, ductile dimples, cleavage, etc., the interior pore surfaces add complications to a fractographic analysis. The smooth surfaces of the inherent porosity are not only common with PM materials, they are expected. Part density, the effectiveness of sintering, and the history of the part in the green state have large effects on the microstructure and subsequently, on the appearance of the broken surfaces. The fraction of pore edges, which appear as smooth free particle surfaces, varies with density, where low-density regions display large amounts of these free surfaces. Sintering causes the particles forced into intimate contact during compaction to form metallurgical bonds. Better sintering results in neck growth and a more homogeneous distribution of alloying elements. Inappropriate handling of green parts or compaction/ejection problems can create internal cracks within the parts prior to sintering.

Techniques will be presented both to prepare surfaces for analysis and to quantify the appearance of fracture surfaces. Examples of PM materials broken using different types of loading will be used to demonstrate the use of these methods. In addition, an investigation using an FC-0205 material was conducted to investigate the effects of the three variables mentioned above. Test pieces were compacted to several densities and sintered using various temperatures to produce density and sinter quality variations. In addition, cracks were introduced into green test pieces and examined after sintering. SEM analysis of the fractures was used in concert with light microscopy on prepared cross-sections to evaluate and quantify the resulting fracture surfaces.

196. Sintering of Powder Premixes - A Brief Overview Advances in the understanding of the sintering of powder premixes have contributed significantly to the growth of the ferrous powder metallurgy industry. This includes sintering both in the solid state and in the presence of a liquid phase. In this article, the sintering of iron powder premixes containing: 1) graphite; 2) nickel and graphite; 3) copper and graphite; 4) Phosphorus as ferrophosphorus; and, 5) boron as ferroboron are discussed. The evolution of microstructure and mechanical properties are discussed as well.
157. Quantifying the Degree-of-Sinter in Ferrous P/M Materials Improvements in the physical and mechanical properties of pressed and sintered ferrous materials are made during the sintering process. Particle bonding and alloying by diffusion occur during sintering with property enhancements resulting as the sintering time is increased. The effects of sintering are visible as changes in microstructural features, such as particle boundaries and pore edges. Some of the improvements in sintering appear as a loss in particle boundaries, smoother pore edges, and a lessening in the number of angular features between particles. The appearance of these features and characteristics, in conjunction with their frequency of occurrence, is often referred to as degree-of-sinter. Quantification of the degree-of-sinter can be performed on properly prepared metallographic specimens using well-understood stereological practices. Three test methods will be discussed as techniques for quantifying and separating materials sintered to varying degrees. Additionally, images of an iron-copper-carbon premix, sintered at varying times, will be used to illustrate these microstructural changes.

 



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