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194. Effect of Post Sintering Thermal Treatments on Dimensional Precision and Mechanical Properties in Sinter-Hardening PM Steels Dimensional precision is a critical parameter in net shape processing of ferrous PM components. PM parts producers continue to pursue larger parts, but absolute tolerances dictated by the end user generally do not scale with part size. Therefore, in larger parts, the variation in percentage change in size, or dimensional change, must be reduced. Beyond the dimensional changes associated with pressing and sintering of typical low alloy PM steels, sinter-hardenable alloys present some unique challenges and opportunities for PM part manufacturing. The ability to harden a part in the sintering furnace eliminates the need for a secondary quenching operation. The resulting microstructure of untempered martensite is, however, not ideal for dimensional stability and mechanical properties. Tempering hardened steels results in improved mechanical properties and dimensional shrinkage, as the martensite converts to a more stable ferrite and carbide microstructure of higher density. In addition, many sinter-hardening grades contain high Cu and C contents that result in relatively high amounts of retained austenite. Retained austenite can improve impact and ductility properties, but contributes to dimensional instability as it can transform to lower density bainite and/or martensite with thermal fluctuations. Proper thermal treatments of sinter-hardened steels are necessary to obtain the best combination of mechanical properties and dimensional control. This paper reviews the effects of different post-sintering thermal treatments on the dimensional, microstructural and mechanical property changes of sinter-hardened PM steels.
186. Dimensional Precision in Sinter-Hardening PM Steels Dimensional precision is a critical parameter in net shape processing of ferrous PM components. Beyond the dimensional changes associated with pressing and sintering of typical low alloy PM steels, sinter-hardening alloys undergo a transformation from austenite to martensite. The formation of martensite results in a large expansion during cooling, as martensite is the lowest density phase in steels. Tempering hardened steels results in shrinkage, as the martensite converts to a ferrite and carbide microstructure of higher density. Both of these transformations have a large impact on the dimensional change. In addition, martensitic regions with high Cu and C contents may contain large amounts of retained austenite. As austenite is the highest density phase, retained austenite results in less growth of the compact. The presence of martensite and retained austenite, in addition to the tempering step, all play a role in the final dimensions of a component. This paper reviews two sinter-hardening grades and investigates the dimensional and microstructural changes of those grades through different post-sintering thermal treatments.
184. Dimensional Control in Cu-Ni Containing Ferrous PM Alloys Elemental additives, such as copper and nickel, modify the dimensional change in sintered parts. Typically, Cu causes growth and Ni causes shrinkage. Interactions between Cu, Ni and C complicate these simple trends leading to more complex behavior. With the use of prealloyed Mo base materials, these alloy systems can be used for sinter-hardening applications. This paper investigates the dimensional and microstructural changes of Cu-Ni containing PM alloys during the sintering process.

 



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